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Definition

Buffer Solution

  • A system that minimizes changes in pH when small amounts of acid or base are added.

Components

  • Weak Acid and its Conjugate Base (e.g., acetic acid and sodium acetate).

  • Weak Base and its Conjugate Acid (e.g., ammonia and ammonium chloride).

Mechanism of Buffer Action

Acidic Buffers

  • Addition of Acid (H⁺): The conjugate base (A⁻) reacts with H⁺ to form the weak acid (HA), minimizing pH change.

Acidic Buffers: Addition of Acid
  • Addition of Base (OH⁻): The weak acid (HA) donates H⁺ to form water and the conjugate base (A⁻).

     

Acidic Buffers: Addition of Base

Basic Buffers

  • Similar reactions occur with a weak base and its conjugate acid.

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