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Classification of Histamine

  • Histamine is a biogenic amine derived from the decarboxylation of the amino acid histidine.

  • It plays pivotal roles in immune responses, gastric acid secretion, and as a neurotransmitter.

Structure of Histamine
Structure of Histamine

Synthesis:

  • From the amino acid histidine by the enzyme histidine decarboxylase.

Storage:

  • Primarily stored in mast cells (in tissues) and basophils (in blood). Also found in the brain as a neurotransmitter.

Release Triggers:

  • Allergic reactions (type I hypersensitivity reactions).

  • Tissue injury or mechanical trauma.

  • Certain drugs and chemicals.

Functions of Histamine:

  • Immune Response: Mediates inflammation and allergic reactions by increasing vascular permeability and attracting immune cells.

  • Gastric Secretion: Stimulates parietal cells in the stomach to produce hydrochloric acid.

  • Neurotransmission: Involved in wakefulness and cognitive functions.

Histamine Receptors:

  • Histamine exerts its effects through four types of receptors, designated H1 to H4, each with distinct locations and functions.

Histamine Receptors
Histamine Receptors

H1 Receptors:

  • Location: Smooth muscles, endothelium, central nervous system.

  • Functions: Mediate allergic symptoms (e.g., vasodilation, bronchoconstriction), contribute to wakefulness.

H2 Receptors:

  • Location: Parietal cells of the stomach, heart.

  • Functions: Stimulate gastric acid secretion, regulate heart rate.

H3 Receptors:

  • Location: Central nervous system, presynaptic neurons.

  • Functions: Modulate neurotransmitter release.

H4 Receptors:

  • Location: Bone marrow and white blood cells.

  • Functions: Involved in immune cell chemotaxis and activation.

Pharmacological Effects of Histamine

  • Vasodilation, particularly of small vessels → decreases blood pressure.

  • Increased capillary permeability → edema and urticaria.

  • Smooth muscle contraction → bronchoconstriction (H1 effect).

  • Gastric acid secretion (H2 effect).

Histamine Antagonists

Histamine Antagonists
Histamine Antagonists

H1 Antagonists (H1 Blockers):

  • Purpose: Primarily used to treat allergic reactions, such as hay fever, urticaria, and allergic conjunctivitis.

  • Examples: Diphenhydramine, cetirizine, loratadine.

  • Mechanism: Block H1 receptors to reduce vasodilation, capillary permeability, and smooth muscle contraction associated with allergic responses.

H2 Antagonists (H2 Blockers):

  • Purpose: Used to reduce gastric acid secretion in conditions like peptic ulcers and gastroesophageal reflux disease (GERD).

  • Examples: Ranitidine (withdrawn in many markets due to safety concerns), famotidine, cimetidine.

  • Mechanism: Block H2 receptors on parietal cells, decreasing the production of stomach acid.

H3 and H4 Antagonists:

  • Current Status: Primarily under research; potential applications in neurological disorders and immune modulation.

  • Below is a concise table summarizing the four histamine receptor subtypes.

Receptor

Location

Signaling Pathway

Key Effects (Actions)

Example Drug (Typically an Antagonist)

H1

Smooth muscle (bronchi, gut), endothelium, brain

Gq → ↑ IP3, DAG

- Bronchoconstriction- Vasodilation (via NO release)- ↑ Vascular permeability- Itching, pain (nerve endings)

Diphenhydramine (1st-gen H1 blocker)

H2

Gastric parietal cells, heart, mast cells, brain

Gs → ↑ cAMP

- ↑ Gastric acid secretion- Positive inotropic & chronotropic effects on the heart

Ranitidine (H2 blocker)

H3

Presynaptic nerve terminals (mainly in the CNS)

Gi → ↓ cAMP

- Inhibition of histamine release (auto-receptor)- Modulation of neurotransmitter release

Pitolisant (H3 inverse agonist/antagonist)

H4

Hematopoietic cells (eosinophils, T cells, mast cells)

Gi → ↓ cAMP

- Chemotaxis & inflammation- Role in immune cell activation

Still under research (no major drug in use)

Note:

  • H1 antagonists (antihistamines) are often used for allergic conditions, motion sickness, etc.

  • H2 antagonists are used for peptic ulcers and acid reflux (GERD).

  • H3 antagonists/inverse agonists have emerging roles in sleep-wake regulation (e.g., Pitolisant for narcolepsy).

  • H4 antagonists are still in experimental stages, mainly targeting inflammatory and immune disorders.


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