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Concept of Oxidation

  • Oxidation is a process in which a chemical species loses one or more electrons, leading to an increase in its oxidation state.

  • In simpler terms, the species becomes more positively charged.

  • Oxidation is often associated with the addition of oxygen to a substance or the removal of hydrogen from it.

  • However, the key factor that defines oxidation is the loss of electrons.

illustration of the concept of oxidation
illustration of the concept of oxidation

Example:

  • Consider the reaction between magnesium metal (Mg) and oxygen gas (O2) to form magnesium oxide (MgO).

Mg (s) + 1/2 O2 (g) -> MgO (s)

  • In this reaction, magnesium loses two electrons to become the Mg^2+ ion, as shown below:

Mg (s) -> Mg^2+ (s) + 2e^-

  • Magnesium has been oxidized, as it has lost electrons, and its oxidation state has increased from 0 to +2.

Oxidizing agents:

  • An oxidizing agent is a substance that gains electrons in a redox reaction, causing the oxidation of another species.

  • By accepting electrons from another species, it enables the other species to lose electrons, leading to its oxidation.

  • As a result, the oxidizing agent itself gets reduced in the process. Oxidizing agents typically have a high affinity for electrons and can be identified by their ability to cause the oxidation of other substances.

Example:

  • In the reaction between hydrogen gas (H2) and oxygen gas (O2) to form water (H2O):

2H2 (g) + O2 (g) -> 2H2O (l)

  • Oxygen (O2) is the oxidizing agent, as it gains electrons from hydrogen (H2) during the reaction, leading to the reduction of oxygen and the oxidation of hydrogen.


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