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Electrophilic addition is a fundamental chemical reaction where an electrophile and a nucleophile, typically an alkene or alkyne, combine to form a single bond.
This process involves the conversion of a π bond into new σ bonds, playing a crucial role in the transformation of alkenes and alkynes into more complex organic compounds.
Key Concepts of Electrophilic Addition:
1) Electrophiles and Nucleophiles:
Electrophiles are electron-deficient species that seek electrons.
Nucleophiles are electron-rich species ready to donate electrons.
Alkenes and alkynes act as nucleophiles due to their electron-rich π bonds.
2) Mechanism:
The reaction proceeds in two main steps:
Step 1: Electrophilic Attack: The electrophile attacks the electron-rich π bond, forming a carbocation intermediate.
Step 2: Nucleophilic Attack: The nucleophile then attacks the carbocation, forming a new σ bond.
Example: Addition of HBr to Ethene
Step 1 - Electrophilic Attack:
HBr's proton (H⁺) acts as the electrophile, attacking the ethene's π bond, forming a carbocation and a bromide ion (Br⁻).
H₂C=CH₂ + HBr → H₂C-CH₂⁺ + Br⁻
Step 2 - Nucleophilic Attack:
The bromide ion (Br⁻) then attacks the carbocation, forming bromoethane.
H₂C-CH₂⁺ + Br⁻ → H₂C-CH₂Br
Significance:
Electrophilic addition is vital in organic synthesis, allowing for the introduction of functional groups into alkenes and alkynes.
This versatility makes it indispensable in creating a myriad of organic compounds, including polymers, pharmaceuticals, and agrochemicals.
By employing different electrophiles, such as hydrogen halides (HX), halogens (X₂), and water (H₂O), chemists can synthesize a diverse range of functionalized molecules through this reaction mechanism.
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