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Instrumentation of Affinity Chromatography

  • A typical affinity chromatography setup comprises the following components:

Pump:

  • Ensures a consistent and controlled flow of the mobile phase (sample solution and elution buffer) through the affinity column.

  • High-pressure pumps are commonly used for faster runs.

Sample Injector:

  • Allows precise introduction of the sample into the chromatography system.

  • Auto-samplers can load multiple samples sequentially for high-throughput applications.

Affinity Column:

  • The core component containing the immobilized ligand specific to the target molecule.

  • Typically made of materials like agarose, sepharose, or other polymeric beads covalently linked with the ligand.

Detectors:

  • Monitor eluted compounds from the column.

  • Common types include:

  • Ultraviolet (UV) Detector: Detects compounds based on absorbance at specific wavelengths, useful for most organic molecules.

  • Fluorescence Detector: For molecules that fluoresce or are labeled with fluorescent tags.

  • Conductivity Detector: Monitors changes in solution conductivity, useful when elution involves changes in ionic strength.

Fraction Collector:

  • Collects separated compounds into distinct fractions for further analysis or use.

Temperature Control Unit:

  • Maintains specific temperature conditions required for stability or optimal binding/elution.

Recorder/Data System:

  • Interfaces with computers for real-time data acquisition, analysis, and visualization.

  • Essential for peak identification, quantification, and data storage.


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