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Introduction to Iridoids, Other Terpenoids & Naphthoquinones

Iridoids

  • Structure of Iridoids: Derived from monoterpenes with a cyclopentane[c]pyran ring, often occurring as glycosides hydrolyzed to release active aglycones.

  • Plant Functions: Serve as defense compounds (bitter and toxic), aid in signaling, and deter herbivores and pathogens.

Other Terpenoids

  • Structure: Derived from isoprene units (C5), forming diverse structures such as monoterpenes, sesquiterpenes, and diterpenes.

  • Plant Roles:

    • Ecological Interactions: Attract pollinators, repel herbivores, or act as chemical signals.

    • Protection: Many exhibit antimicrobial, antifungal, or anti-inflammatory properties.

  • Pharmacological Importance: Used in traditional medicine, food flavoring, and as precursors for pharmaceuticals.

Naphthoquinones

  • Structure: Naphthalene ring with two carbonyl groups; conjugation often gives bright colors (yellow to red).

  • Biological Roles:

    • Function as pigments.

    • Defensive properties include generating reactive oxygen species and disrupting cellular processes in predators or pathogens.

  • Pharmacological Potential: Possess antimicrobial, antiviral, and anticancer activities, making them valuable for therapeutic applications.


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