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Procaine

Structure

  • Procaine Chemical Structure – C13H20N2O2

Procaine

Mode of action

  • Procaine primarily affects peripheral neurons by blocking sodium inflow through voltage-gated sodium channels in the neuronal cell membrane.

  • An action potential cannot form when the influx of sodium is inhibited, and signal conduction is so blocked.

Structure-Activity Relationship (SAR) of Procaine

  • Procaine is a local anesthetic used primarily to reduce the sensation of pain in specific areas of the body.

Its SAR can be summarized as follows:

1. Ester Linkage:
  • Procaine is an ester-linked local anesthetic, similar to benzocaine.

  • The ester linkage is crucial for its local anesthetic activity.

  • It is generally associated with a shorter duration of action and a lower incidence of allergic reactions compared to amide local anesthetics.

2. Aromatic Ring:
  • The presence of an aromatic ring (benzene) is essential.

  • This part of the molecule is lipophilic, aiding in its ability to penetrate cell membranes to reach its site of action in nerve cells.

3. Amino Group:
  • The para-position amino group on the benzene ring is important for anesthetic activity.

  • This group increases the solubility of the compound in biological fluids.

4. Diethylamino Ethanol Side Chain:
  • The diethylamino ethanol side chain is crucial for procaine’s activity.

  • The length and nature of this side chain can significantly affect the drug’s potency and duration of action.

Structure-Activity Relationship (SAR) of Procaine:

Here is the mind map illustrating the Structure-Activity Relationship (SAR) of Procaine:

Synthesis of Procaine

  • The synthesis of Procaine typically involves the following key reaction:

Esterification of Para-Aminobenzoic Acid:
  • C7​H7​NO2 ​+ C6​H1​4N2​O C1​3H2​0N2​O2 ​+ H2​O 

  •  In this reaction, para-aminobenzoic acid (C7H7NO2) is esterified with diethylamino ethanol (C6H14N2O) to form Procaine (C13H20N2O2), along with the production of water (H2O).

  • This synthesis is a classic example of esterification, a common method in organic chemistry for forming ester compounds.

  • The reaction typically involves an acid catalyst and must be carried out under controlled conditions to ensure the purity and yield of the procaine.

Uses

  • Procaine is used for spinal nerve block, peripheral nerve block, and anaesthesia.


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