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General Introduction

  • Rauwolfia alkaloids are indole alkaloids known primarily for their sedative and antihypertensive effects.

  • They have been used extensively in traditional medicine for treating hypertension and mental disorders.

  • Rauwolfia
    Illustration of Rauwolfia

Synonyms

  • Common Name: Indian snakeroot alkaloids

  • Scientific Name: Rauwolfia serpentina alkaloids

  • Other Names: Reserpine, Ajmaline, Serpentine alkaloids

Biological Source

  • Plant: Extracted from the dried roots of Rauvolfia serpentina.

  • Family: Apocynaceae

Composition

  • Major Alkaloids: Reserpine, Ajmaline, Ajmalicine, Serpentine.

Chemistry & Chemical Classes

  • Chemical Class: Indole alkaloids

  • Structure Details:

  • Reserpine features a yohimbine-type skeleton with a methoxybenzoyl group.

  • Ajmaline contains an indole moiety with a unique polycyclic structure.

  • Solubility: Primarily lipophilic; however, water-soluble salts are formed for therapeutic use.

Therapeutic Uses

  • Reserpine: Used as an antihypertensive agent by depleting catecholamines and serotonin from peripheral nerve endings.

  • Ajmaline: Acts as an antiarrhythmic agent in the treatment of cardiac arrhythmias.

  • Ajmalicine: Employed for peripheral vasodilation and in treating Raynaud's disease.

Commercial Applications

  • Reserpine: Available in tablet form for hypertension and mild psychosis.

  • Ajmaline: Marketed as an injectable for arrhythmia management.

  • Widely exported for various pharmaceutical applications.


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