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Sodium Bicarbonate (NaHCO₃)

Properties Sodium Bicarbonate:

  • White crystalline powder

  • Odorless

  • Soluble in water

  • Slightly alkaline taste

  • Decomposes at high temperatures

  • Chemical formula: NaHCO₃

Preparation (Solvay Process):

  • Prepared industrially by passing carbon dioxide and ammonia through a concentrated sodium chloride (brine) solution.

  • Chemical Reaction:

  • "NaCl"+〖"NH" 〗_3+〖"CO" 〗_2+"H" _2"O" →〖"NaHCO" 〗_3+〖"NH" 〗_4"Cl"

  • Sodium bicarbonate precipitates out and is then filtered, washed, and dried.

Uses:

  • As a systemic antacid to treat acid indigestion, heartburn, and upset stomach.

  • As a leavening agent in baking.

  • As an odor neutralizer and cleaning agent.

  • In the management of metabolic acidosis and certain drug overdoses (under medical supervision).

Assay of (Acid-Base Titration):

  1. Prepare a Standard Solution: Dissolve a known amount of a strong acid, such as hydrochloric acid (HCl), in water to create a solution with a known concentration.

  2. Sample Preparation: Weigh an accurate amount of NaHCO₃ and dissolve it in water.

  3. Add Indicator: Add a pH indicator, such as phenolphthalein, to the NaHCO₃ solution. The indicator changes color at neutralization.

  4. Titrate: Slowly add the standard HCl solution to the NaHCO₃ solution while stirring. NaHCO₃ reacts with HCl, forming water, carbon dioxide (CO₂), and sodium chloride (NaCl). The endpoint is reached when the indicator changes color.

  5. Calculate Concentration: Measure the volume of HCl used in the titration to calculate the concentration or purity of NaHCO₃.


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